Suau'u Silicone o se ituaiga polysiloxane ma tikeri eseese o le fausaga o filifili polymerization.E faia i le dimethyldichlorosilane e ala ile hydrolysis ma le vai e maua ai le mama polycondensation muamua.Ua ta'e le tino mama ma toe fa'asa'o e maua ai le tino mama maualalo.Ona tuʻufaʻatasia ai lea o le tino mama, ulu faʻamaufaʻailoga ma catalyst mo polycondensation e maua ai le tele o faʻafefiloi ma tikeri eseese o polymerization.A maeʻa ona aveese le mea faʻafefe maualalo e ala ile faʻamama faʻamama, e mafai ona gaosia le suauu silicone.
E masani ona faʻaaogaina le suauʻu silicone, o vaega faʻalenatura o methyl uma, e taʻua o le methyl silicone oil.E mafai fo'i ona fa'aoga isi vaega fa'aletino e sui ai nisi vaega methyl ina ia fa'aleleia ai nisi o meatotino o le suau'u silicone ma fa'aoga i fa'amoemoega eseese.O isi vaega masani o le hydrogen, ethyl, phenyl, chlorophenyl, trifluoropropyl, ma isi. I tausaga talu ai nei, ua vave ona atiaʻe le suauʻu silicone faʻaleleia, ma o loʻo i ai le tele o suauʻu suauʻu faʻasolosolo faʻasolosolo ma mea faʻapitoa.
Jiangxi Huahao Chemical Co., Ltd.
O le suauu silikoni e masani lava e leai se lanu (poʻo samasama samasama), leai se tofo, e le oona, e le faʻafefe vai.O le suauu silikoni e le mafai ona faʻafefe i le vai, methanol, glycol ma - ethoxyethanol.E fa'afefiloi ma le benzene, dimethyl ether, methyl ethyl ketone, carbon tetrachloride po'o kerosene.E solu teisi i le acetone, dioxane, ethanol ma le ava malosi.E itiiti le mamafa o le ausa, maualuga le moli ma le afi, ma maualalo le malulu.Faatasi ai ma le numera eseese o vaega filifili n, ua faateleina le mamafa mole ma faateleina foi le viscosity.E iai viscosities eseese mo le faʻapipiʻiina o le suauʻu silicone, e amata mai i le 0.65 centistokes i le faitau miliona o centistokes.Afai e tatau ona saunia le suauʻu silikoni maualalo, e mafai ona faʻaaogaina le omea acid e fai ma faʻamalosi ma polymerized i le 180 ℃, poʻo le sulfuric acid e mafai ona faʻaaogaina e fai ma faʻamalosi ma polymerized i le vevela maualalo e maua ai le suauʻu silikoni maualuga poʻo mea viscous.
E tusa ai ma le fausaga o vailaʻau, e mafai ona vaevaeina le suauʻu silicone i le methyl silicone oil, ethyl silicone oil, phenyl silicone oil, methyl hydrosilicone oil, methyl phenylsilicone oil, methyl chlorophenyl silicone oil, methyl ethoxy silicone oil, methyl trifluoropyl silicone oil, methyl vinyl silicone. suauu, suauu methyl hydroxysilicone, suauu ethyl hydrosilicone, suauu hydroxyhydrosilicone, suauu cyanogen silicone, suauu hydrosilicone maualalo, ma isi;mai le faʻamoemoe, o loʻo maua le suauʻu silicone faʻafefe.Suau'u, suau'u suau'u suau'u fa'asalalauina, suau'u suau'u, suau'u fa'amama, suau'u vevela, suau'u taofi, ma isi.
O le suauu silikoni e sili ona lelei le vevela, faʻafefe eletise, faʻafefe o le tau, hydrophobicity, physiological inertia ma le laʻititi laʻititi, faʻaopoopo i le maualalo o le vevela o le vevela, maualuga faʻamalosi faʻamalosi) o nisi ituaiga e iai foʻi le faʻamalositino.
Jiangxi Huahao Chemical Co., Ltd. o lo'o i Xinghuo Industrial Park.Na faavaeina ia Novema 2011 ma e aofia ai se vaega e sili atu i le 30 mu.I le 2014, o le vaega I Poloketi (4500t / a silicone series oloa) na faʻaaogaina ma talia.O oloa autu o: suauʻu suauʻu hydroxy, suauʻu dimethylsilicone, suauʻu hydrogen silikoni maualalo, suauʻu silicone faʻaleleia polyether ma 107 paʻu.I le 2017, na faʻatamaoaigaina ai oloa faʻasolosolo i lalo, faʻateleina le suauʻu vinyl silicone, amino silicone suauʻu ma silanes, e aofia ai le methyltrimethoxysilane, methyltriethoxysilane ma le methylsilicic acid, ma faʻaleleia atili ai le ituaiga o suauʻu silicone hydrogenated, ma le tasi itu hydrogen i le amataga, ma fa'atuputeleina fa'au'u o le hydrogen ma isi mea fa'apipi'i fa'a-hydrogenated.I le taimi nei, o loʻo suʻesuʻeina le suauʻu silikoni maualuga e mafai ona suitulaga i le methyl silicone.Amata ona faʻagaioia i le vaega III poloketi i le 2018, o oloa e aofia ai le heptamethicone, polyether modified silicone oil, silazane, silicon ether, dimethyldiethoxysilane ma isi oloa.
Silicone Emulsion
Silicone emulsion o se ituaiga o suauu silicone.O mea nei o lo'o fa'afeiloa'i mai vaega e lua: fa'amalulu suau'u silicone ma fa'ama'i emulsion defoamer suau'u silicone.
I. silicone suauu ie faamaluluina
Silicone emulsion e masani ona faʻaaogaina e fai ma faʻamalulu mo ie suauu silicone.O le augatupulaga muamua o le faʻamaeʻaina o le ie silicone o se faʻafefiloi masini o le suauʻu dimethylsilicone ma le suauʻu hydrosilicone (ma ona mea e maua ai).O le augatupulaga e lua o le organosilicon ie faamaea sui o le hydroxyl faamutaina poly lua methyl siloxane emulsion.E faia e le emulsion polymerization o le valu mama methyl fa siloxane monomer, vai, emulsifier, catalyst ma isi mea mata i lalo o nisi tulaga.Talu ai ona o le polymerization ma le emulsification ua maeʻa i le laasaga e tasi, o loʻo i ai le lelei o itula faigaluega puʻupuʻu, maualuga galuega lelei, meafaigaluega faigofie ma faʻaoga faigofie.O le emulsion maua mai e matua mautu, ma o vaega e matua tutusa.O le polymer malosi (hydroxyl) i pito uma e lua o le polymer e mafai ona toe faʻaleleia atili e fausia ai se ata tifaga, lea e faʻaleleia ai le faʻaleleia o le faʻaogaina o le faʻaogaina o le emulsion, lea e le lava mo le suauʻu silicone emulsified masini.
Hydroxyl silicone suauu emulsion e mafai ona vaevaeina i le tele o ituaiga o emulsion, e pei o le cation, anion, ions nonionic ma tuufaatasia, e tusa ai ma le eseese surfactants faaaogaina.
1. cationic hydroxyl silicone suauu emulsion
O le emulsifier faʻaaogaina i le cationic emulsion polymerization e masani lava quaternary amine masima (octadecyltrimethyl ammonium chloride lipotia i Foreign Literature), ma le catalyst o le ammonium hydroxide.E mafai ona fa'aogaina le susu cationic hydroxyl i 'ie 'ese'ese pe a mae'a.O loʻo i ai mea totino o le faʻaleleia atili o le 'au o le ie, faʻaleleia atili o le elasticity ma le lamolemole.E i ai se isi tulaga fa'apitoa: o le su'esu'ega fa'alelei lelei mo ie, e fetaui ma le methyl hydrogen silicone suau'u emulsion, fa'afefe ma le fa'asusu le tumau.E mafai ona faʻaaogaina e fai ma sui e faʻafefe vai mo polyester ufiufi tapoleni ma sui susu mo ie pepa polyester.Ma faapena atu ai lava.
2. anionic hydroxyl silicone suauu emulsion
O le susu anionic hydroxyl o lo'o fa'aalia i lona fetaui lelei i le sui fa'auma ie, ma o le emulsion e matua mautu.Aemaise lava, o le tele o ausilali i lomitusi ie ma vali o le anionic.Afai e faʻaaogaina cationic hydroxy emulsion, e faigofie ona mafua ai le demulsification ma le suauʻu bleaching, aʻo emulsion anionic hydroxy e mafai ona aloese mai lenei faʻaletonu, o lea e sili atu ona lauiloa i tagata faʻaoga ma faʻaaogaina lautele.
3. emulsion suauu ionic hydroxyl silicone tuufaatasia
E ui lava o le cationic hydroxyapatite o se faʻamalulu ie sili ona lelei, o lenei emulsion e le faʻasaʻo i vai malo ma e le mafai ona faʻaaogaina i le dimethylolyl lua hydroxyurea urea resin.
E ui lava o le cationic hydroxyapatite o se faʻamalulu ie sili ona lelei, o lenei emulsion e le mafai ona faʻafefe i le vai malulu, ma e le mafai ona faʻaaogaina i le taele tutusa ma le dimethoxylated lua hydroxyvinyl urea resin (2D) resin, catalyst magnesium chloride ma le anionic sui sooupu.E le gata i lea, ona o le le lelei o le mautu o le emulsion, o polymers silicone e faigofie ona vavae ese mai le emulsion ma faʻafefe i luga o le vai, e masani ona taʻua o le "suauʻu bleaching".Afai o le cationic ma non-ionic emulsifiers e faʻaaogaina i le polymerization emulsion, e mafai ona faatoilaloina le faaletonu o le cationic emulsifier mo le saunia o le suauʻu suauʻu hydroxyl silicone.O le emulsion silicone saunia e mafai ona tatalia le vai malo, ma e mafai ona faʻaaogaina i totonu o le taele tutusa ma le 2D resin, magnesium chloride ma le paʻepaʻe VBL, ma e lelei le vevela ma le malulu.
4. non ionic hydroxyl silicone suauu emulsion
Ole susu ole vai e sili atu le fetuutuunai ma le mautu nai lo le susu hydroxy tu'ufua, o le tele o atunu'u ua faia taumafaiga tetele e su'esu'e le susu e le ninionic hydroxy.Mo se faʻataʻitaʻiga, UltrateX FSA, o se oloa fou na faia i Suitiselani, o se emulsion non-ionic ma le mamafa mole mole sili atu i le 200 afe ma le ulu hydroxyl o le lua methylsiloxane.O se laasaga i luma nai lo le Dc-1111 anionic hydroxyapatite emulsion i le Iunaite Setete.
5. Organosilicon faʻamaeʻaina sui ma isi vaega toaga
Ina ia faʻafetaui manaʻoga o le faʻamaeʻaina faʻamaeʻaina o ituaiga uma o ie, faʻaleleia le suauʻu faʻamaʻi, anti-static ma hydrophilic meatotino o ie faʻamaeʻaina silicone, ma faia ie filo vailaʻau e tele mea lelei o ie masani, tagata faigaluega silicone ua suʻesuʻeina le faʻaofiina o isi vaega malosi e pei o le vaega amino, vaega amide, vaega ester, vaega cyano, vaega carboxyl, vaega epoxy, ma isi. O le faʻaofiina o nei vaega e faia ai le organosilicon ie faʻamaeʻaina sui faʻapitoa faʻapitoa, mo se faʻataʻitaʻiga, o le faʻaofiina o le vaega amino i le mole o le organosilicon e fetaui lelei mo le fa'amae'a muamua ma le fa'amae'aina o fulufulu mamoe;o le faʻaofiina o le vaega amide e talafeagai mo le faʻamaeʻaina o le antifouling, ma o le a faʻaleleia atili le vaivai: o le faʻaofiina o le cyano vaega e lelei le faʻafefe o le suauu, ma o le anti-static aafiaga o le copolymer o le polyoxyethylene ether ma le organosilicon e lelei;o le organofluorine suia organosilicon ua i ai le suauu repellency.Anti filogia, anti-static, vai repellent ma le tele o isi tulaga lelei.
Lua.Silicone suauu emulsion defoamer.
Silicone suauu emulsion defoamer e masani lava suauu i le vai (O / W) emulsion, o lona uiga, vai o se vaega faifai pea, suauu silicone o se vaega discontinuous.E muamua fefiloi ma le suauu silicone, emulsifier ma thickening sui, ona faasolosolo malie lea ona faaopoopo vai e faafefiloi ai, faasolosolo olo i le colloid mill seia maua le emulsion manaomia.
Silicone suauu emulsion defoamer o se sui defoaming lautele faaaogaina i silicone defoamer.E mafai ona faʻaaogaina lautele e pei o le defoamer i le aqueous system.A faʻaaogaina, e mafai ona faʻapipiʻi saʻo le emulsion i le faiga faʻafefe, ma e mafai ona maua lelei le faʻaleagaina.Ina ia faʻaleleia le faʻaleagaina o le faʻafefe o le emulsion ma le saʻo o le fuaina, e masani lava e le faʻaaogaina saʻo nai lo le 10% o le suauʻu suauʻu silikono faʻapipiʻi: muamua, e faʻafefe i le 10% pe itiiti i le vai malulu pe tuusaʻo ma le fofo faʻafefe.O tapu e tatau ona faʻafefe i le vevela poʻo le faʻaitiitia o le vai, a leai o le a mafua ai le faʻaleagaina o le emulsion.O le mautu o le emulsion o le a sili atu ona leaga pe a uma ona faʻafefeteina, ma faʻapipiʻi (suauu bleaching) mea e mafai ona tupu i le teuina o le faagasologa, o lona uiga, demulsification.O le mea lea, e tatau ona faʻaaogaina le emulsion faʻafefeteina i se taimi vave e mafai ai.Afai e manaʻomia, e mafai ona faʻaopopo mea mafiafia e faʻaleleia ai le mautu o le emulsion.Mo le fa'agaioiga fa'atosina, e mafai ona fa'aopoopo le suau'u silicone emulsion a'o le'i fa'agasolo le faiga po'o fa'atasi.Mo le faʻagaioiga faʻaauau, e tatau ona faʻaopoopo le suauʻu silicone emulsion faʻaauau pe faʻalavelave i vaega talafeagai o le faiga.
I le faʻaaogaina o emulsion defoamers, o le vevela ma le gaʻo ma tulaga alkaline o le faiga faʻafefe e tatau ona amanaia.Ona o le suauʻu silicone emulsion e sili atu ona maaleale, o lona emulsion o le a demulsified muamua, ma o le a le lelei pe le aoga.Ole aofaiga ole suau'u silicone emulsion e masani lava 10 i 10Oppm o le mamafa o le vai foaming (e tusa ai ma le mita suauu silicone).Ioe, o loʻo i ai foi i lalo ifo o le 10 ppm ma sili atu nai lo le 100 ppm i mataupu faʻapitoa.Ole fua talafeagai e fa'atatau ile su'ega.
E masani lava, silicone suauu emulsion defoamer o le tele o suauu i le vai.E tusa ai ma ituaiga eseese o suauu silicone, silicone suauu emulsion defoamer ei ai ituaiga nei:
1. suau'u silicone emulsion fa'avae i luga ole suāu'u methyl silicone
O lenei ituaiga defoamer e faia i luga ole suauu dimethylsilicone, emulsifier ma vai.E mafai ona faʻaaogaina lautele i le faʻafefeteina, meaʻai, fai pepa, fiber, fale talavai, resini gaosia ma isi.
2. suau'u silicone emulsion fa'avae ile suau'u methyl ethoxy silicone
O lenei ituaiga defoamer e faia i le methyl ethoxy silicone suauu ma lona sui sooupu.
3. suau'u silicone emulsion fa'avae ile suau'u ethyl silicone
I tausaga talu ai nei, o le organosilicon defoamer o loʻo atinaʻe agai i le poloka copolymerization (poʻo le faʻapipiʻiina o le copolymerization) o le polyether organosilicon.O lenei ituaiga defoamer o loʻo i ai uiga o le organosilicon ma le polyether, o lea e faʻaleleia atili ai le malosi faʻafefe;organosilicon polyether copolymer defoamer, e lauiloa foi o le tagata emulsifying organosilicon defoamer, o se filifili ethylene oxide hydrophilic po o le ethylene oxide propylene oxide filifili poloka (po o le sulu) i le filifili mole mole organosilicon, ina ia tuufaatasia le vaega hydrophobic siloxane ma le polyether hydrophilic.I le avea ai o se mea faʻafefe, o sea mole e i ai se faʻasalalauga tele, e mafai ona faʻasalalau tutusa i totonu o le ala faʻafefe, ma e maualuga lona lelei.O se ituaiga fou o le fa'amama fa'alelei maualuga.O le emulsifying aafiaga o le tagata lava emulsifying silicone suauu e aunoa ma emulsifier e fai lava si faamalieina mo nisi faiga.E sili ona talafeagai mo i latou e le talafeagai mo le suauʻu suauʻu silicone lautele emulsion suauu silicone lautele.
Taimi meli: Sep-24-2022